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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Regioselective and Direct Azidation of Anilines via Cu(II)-Catalyzed C-H Functionalization in Water.
Journal of Organic Chemistry 2017 October 21
We report herein the first example of Cu(II)-catalyzed site selective azidation of aromatic amines via C-H functionalization in aqueous media. In our strategy, a mild reagent was utilized. H2 O2 served as the oxidant, and sodium azide was used as the azidation reagent. This method could also be applied to late-stage functionalization of drugs that possess an aromatic amine moiety. In addition, we found that bromination or iodination on the ortho-position of aromatic amines could occur efficiently using this catalytic system.
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