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Synthesis and characterization of 8-hydroxyquinolin-1-ium 2,2,2-trifluoroacetate and 8-hydroxyquinolin-1-ium 2,2,2-trichloroacetate by z-scan technique.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy 2018 Februrary 6
The 8-hydroxyquinolin-1-ium 2,2,2-trifluoroacetate and 8-hydroxyquinolin-1-ium 2,2,2-trichloroacetate (8-HQ) salts have been synthesized and characterized by FTIR, NMR and UV-Vis absorption spectroscopic methods. The third order nonlinear optical properties (NLO) of the two 8-HQ salts have been investigated by z-scan technique. The recorded experimental data led to calculate the nonlinear optical absorption coefficient (β), the nonlinear refractive index (n2 ), the excited-state absorption cross section (σex ) and the ground-state absorption cross section (σg ) of the studied compounds. The two 8-HQ salts have been found to exhibit large optical nonlinearity. These types of materials may be considering new photonic applications.
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