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Enantioselective [2,3]-Sigmatropic Rearrangements: Metal-Bound or Free Ylides as Reaction Intermediates?

Katharina J Hock, Rene M Koenigs
Angewandte Chemie 2017 September 19
Out of bounds: Enantioselective rearrangement reactions are a long-standing challenge in organic synthesis. Recent advances are highlighted that led to the development of the first enantioselective Doyle-Kirmse reaction and enantioselective rearrangement reactions of iodonium ylides.

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