Orthogonally Functionalized Donor/Acceptor Homo- and Heterodimeric Dyes for Dye-Sensitized Solar Cells: An Approach to Introduce Panchromaticity and Control the Charge Recombination.

Organic dyes possessing conjugated π-framework forms closely packed monolayers on photoanode in dye-sensitized solar cell (DSSC), because of the limitation to control the orientation and the extend of intermolecular π-π interaction, self-aggregation of dyes leads to reduced cell performance. In this report, a series of homodimeric (D1 -D1 and D2 -D2 ) and heterodimeric (D1 -D2 and D2 -D4 ) donor/acceptor (D/A) dyes containing spiroBiProDOT π-spacer were designed and synthesized by utilizing Pd-catalyzed direct arylation reaction and correlates the device performance with monomeric dyes (D1 and D2 ). Both the thiophenes (π-spacer) of spiroBiProDOT were functionalized with same or different donor groups which led to homodimeric and heterodimeric chromophores in a single sensitizer. The homodimeric spiro-dye D1 -D1 showed higher power conversion efficiency (PCE), of 7.6% with a Voc and Jsc of 0.672 V and 16.16 mA/cm2 , respectively. On the other hand, the monomeric D1 exhibited a PCE of 3.2% (Voc of 0.64 V and Jsc of 7.2 mA/cm2 ), which is lower by 2.4 fold compared to dimeric analogue. The spiro-unit provides flexibility between the incorporated chromophores to orient on TiO2 due to four sp3 -centers, which arrest the molecular motions after chemisorption. This study shows a new molecular approach to incorporate two chromophores in the dimeric dye possessing complementary absorption characteristics toward panchromatic absorption. The attenuated charge recombination at TiO2 /Dye/redox couple interface in case of D1 -D1 , owing to better passivation of TiO2 surface, was elucidated through impedance analysis. The FT-IR spectrum of D1 -D1 adsorbed on TiO2 film indicated both the carboxylic units were involved in chemisorption which makes strong coupling between dye and TiO2 .