Nitrogen-doped carbon nanotubes based on melamine-formaldehyde resin as highly efficient catalyst for oxygen reduction reaction.

The preparation of highly efficient and cheap electrocatalysts toward oxygen reduction reaction is significant for many electrochemical cells. Here we facilely synthesized nitrogen doped carbon nanotube by pyrolyzing melamine formaldehyde resin and Fe loading on MgO. There were mainly three morphologies observed, slender bamboo-like CNT, thick bamboo-like CNT, surface smooth, hollow CNT. The content of Fe loading on MgO had little influence on morphologies of CNT, however, when no MgO as support, only carbon ribbon obtained. The MgO as support was also significant for the formation of CNT. The samples with CNT formed represented better catalytic activity than control samples with no-CNT obtained, the morphology of CNT was beneficial for catalytic process. The sample C1 -CNT with lowest content of Fe on support represented best catalytic activity which was competitive with 20% Pt/C in half-wave potential. The C1 -CNT also showed outstanding stability and improved selectivity towards ORR, making it a promising alternative to Pt in application of fuel cells and metal-air batteries.