Synthesis of CdSe quantum dots decorated SnO 2 nanotubes as anode for photo-assisted electrochemical degradation of hydrochlorothiazide: Kinetic process.

Pharmaceutical residues have been increasingly detected in the aquatic environment and are considered important contaminants of emerging concern. This study examines the photo assisted electrochemical degradation of the Hydrochlorothiazide by using CdSe quantum dots decorated SnO2 nanotubes. The characteristic devices such as Scanning electron microscopy, X-ray diffraction, UV-vis diffuse reflectance Transmission electron Microscopy were used to analyze information structure of CdSe QDs/SnO2 nanotubes. All the experiments were perform with influence of the current density (10-60mAcm-2 ) and sodium chloride (0.02-0.10molL-1 ) in the supporting electrolyte composition was analyzed. The results showed that the Hydrochlorothiazide and TOC removal was achieved in the current density range used. As expected, the degradation kinetics presented a pseudo first order behavior. Comparison of the efficiencies of the photocatalytic, electrochemical (EC) and photo-assisted electrochemical (PAEC) techniques verified that the combined process showed a synergism for HCT and TOC removal.