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Optimized FTO seeding enables the growth of highlyefficient Ta-doped TiO 2 nanorod photoanodes.
Chemical Communications : Chem Comm 2017 September 6
Tantalum doped rutile nanorods were hydrothermally grown on FTO substrates using a new seeding approach. This approach allows the incorporation of high concentrations of up to 4.8 at% tantalum as active doping and results in a significant enhancement of the photoelectrochemical water splitting rate (1.8 mA cm-2 at a potential of +1.5 V vs. RHE) which corresponds to ∼1% photocurrent conversion efficiency under AM 1.5, 100 mW cm-2 simulated sunlight irradiation.
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