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Total syntheses and configuration assignments of JBIR-04 and unantimycin A.
Organic & Biomolecular Chemistry 2017 September 14
First total syntheses of JBIR-04 and unantimycin A have been achieved. Comparison of our spectroscopic data with those reported for natural samples verified the structure of the natural products; (2S,4S,6S,7R,9S,28S) configuration was thus assigned via total synthesis.
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