JOURNAL ARTICLE
RESEARCH SUPPORT, N.I.H., EXTRAMURAL
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Copper(I)/NO (g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO (g) Disproportionation.

A copper complex, [CuI (tmpa)(MeCN)]+ , effectively reductively couples NO(g) at RT in methanol (MeOH), giving a structurally characterized hyponitrito-dicopper(II) adduct. Hydrogen-bonding from MeOH is critical for the hyponitrite complex formation and stabilization. This complex exhibits the reverse redox process in aprotic solvents, giving CuI + NO(g) , leading to CuI -mediated NO(g) -disproportionation. The relationship of this chemistry to biological iron and/or copper mediated NO(g) reductive coupling to give N2 O(g) is discussed.

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