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Highly regio- and stereoselective trans-iodofluorination of ynamides enabling the synthesis of (E)-α-fluoro-β-iodoenamides.
Organic & Biomolecular Chemistry 2017 August 31
A highly regio- and stereoselective trans-iodofluorination reaction of ynamides with NIS and Et3 N·3HF has been achieved, affording (E)-α-fluoro-β-iodoenamides in moderate to good yields. The reaction proceeds under mild reaction conditions and exhibits good functional group compatibility.
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