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Spatial differentiation of Brønsted acid sites by probe molecule in zeolite USY using synchrotron X-ray powder diffraction.

Lin Ye, Ivo Teixeira, Benedict T W Lo, Pu Zhao, S C Edman Tsang
Chemical Communications : Chem Comm 2017 August 30
By combining synchrotron X-ray powder diffraction, Rietveld refinement and the use of a probe molecule, Brønsted Acid Sites (BAS) of different strengths in steam-treated USY zeolite can be for the first time spatially differentiated: this enables the analysis of different acid-catalysed reactions of dimethylfuran (biomass) by the zeolite using a definitive site blockage strategy.

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