Scalable Dry Production Process of a Superior 3D Net-Like Carbon-Based Iron Oxide Anode Material for Lithium-Ion Batteries.

Carbon-based transition-metal oxides are considered as an appropriate anode material candidate for lithium-ion batteries. Herein, a simple and scalable dry production process is developed to produce carbon-encapsulated 3D net-like FeOx /C materials. The process is simply associated with the pyrolysis of a solid carbon source, such as filter paper, adsorbed with ferrite nitrate. The carbon derived from filter paper induces a carbothermal reduction to form metallic Fe, the addition of carbon and iron increase the conductivity of this material. As expected, this 3D net-like FeOx /C composite delivers an excellent charge capacity of 851.3 mAh g(-1) after 50 cycles at 0.2 A g(-1) as well as high stability and rate performance of 714.7 mAh g(-1) after 300 cycles at 1 A g(-1) . Superior performance, harmlessness, low costs, and high yield may greatly stimulate the practical application of the products as anode materials in lithium-ion batteries.