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Flavin-N5-oxide: A new, catalytic motif in flavoenzymology.

Sanjoy Adak, Tadhg P Begley
Archives of Biochemistry and Biophysics 2017 October 16
Flavin-N5-oxide is a recently discovered intermediate used by EncM (1,3-diketone oxidation), DszA (sulfone monooxygenase) and RutA (amide monooxygenase). This review describes the mechanism of these enzymes and proposes criteria for the identification of additional Flavin-N5-oxide dependent enzymes.

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