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Research Support, Non-U.S. Gov't
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Reductive CO 2 Fixation via Tandem C-C and C-N Bond Formation: Synthesis of Spiro-indolepyrrolidines.

Dao-Yong Zhu, Lei Fang, Hui Han, Yazhou Wang, Ji-Bao Xia
Organic Letters 2017 August 19
We describe herein a tandem C-C and C-N bond-forming reaction in the reductive functionalization of CO2 , an abundant and cheap C1 chemical feedstock. This catalytic metal-free CO2 fixation afforded spiro-indolepyrrolidines by dearomatization of tryptamine derivatives with broad scope and good functional group tolerance under mild conditions.

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