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Alkali and alkaline earth metal ion binding by a foldamer capsule: selective recognition of magnesium hydrate.
Chemical Communications : Chem Comm 2017 August 18
Alkali and alkaline earth metal ion binding by an aromatic oligoamide foldamer was shown to induce its folding into a helical capsule. CD and NMR titrations revealed tight and selective binding of Mg2+ . Crystallographic studies demonstrated that, depending on the metal, binding may involve the first or second coordination spheres of the metal hydrates.
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