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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Palladium-Catalyzed Incorporation of Two C1 Building Blocks: The Reaction of Atmospheric CO 2 and Isocyanides with 2-Iodoanilines Leading to the Synthesis of Quinazoline-2,4(1H,3H)-diones.
Organic Letters 2017 September 2
A Pd-catalyzed insertion and cycloaddition of CO2 and isocyanide into 2-iodoanilines under atmospheric pressure has been developed and affords quinazoline-2,4(1H,3H)-diones through the formation of new C-C, C-O, and C-N bonds under mild conditions. This reaction provides a new and practical method not only for the construction of quinazoline-2,4(1H,3H)-diones but also for the efficient utilization of carbon dioxide.
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