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Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates.
Angewandte Chemie 2017 September 19
Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.
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