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Visible light sensitization of benzoyl azides: cascade cyclization toward oxindoles via a non-nitrene pathway.
Chemical Communications : Chem Comm 2017 August 12
Visible light sensitization of benzoyl azides was examined in reaction with N-phenylmethacrylamides to afford biologically important oxindoles and spirooxindoles via a cascade cyclization under mild reaction conditions. Mechanistic studies suggested a non-nitrene pathway, where triplet benzoyl azides act as the reactive intermediate.
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