We have located links that may give you full text access.
A Monte-Carlo simulation of ionic conductivity and viscosity of highly concentrated electrolytes based on a pseudo-lattice model.
Journal of Chemical Physics 2017 July 22
Simulating three transport phenomena-ionic conductivity, viscosity, and self-diffusion coefficient-in a common Monte-Carlo framework, we discuss their relationship to the intermolecular interactions of electrolyte solutions at high concentrations (C/mol l-1 ∼ 1). The simulation is predicated on a pseudolattice model of the solution. The ions and solvents (collectively termed "molecules") are considered dimensionless points occupying the lattice sites. The molecular transport is realized by a repetition of swapping two adjacent molecules by the stochastic Gibbs sampling process based on simple intermolecular interactions. The framework has been validated by the fact that the simulated ionic conductivity and dynamic viscosity of 1:1- and 2:1-salts qualitatively well represent the experimental data. The magnitude of the Coulombic interaction itself is not reflected in the ionic conductivity, but the extent to which the Coulombic interaction is shielded by the dielectric constant has a significant influence. On the other hand, the dielectric constant barely influences the viscosity, while the magnitude of the Coulombic interaction is directly reflected in the viscosity.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app