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Note: Density functional theory for uniformly charged hard-sphere ions.
Journal of Chemical Physics 2017 July 22
The density function theory has been proposed for studying the structural properties of electrolytes containing uniformly charged hard-spherical ions. The calculated result shows good agreement with the corresponding Monte Carlo simulation data of Bohinc et al. [J. Chem. Phys. 145, 234901 (2016)]. The results confirm that the attraction between like-charged planar surfaces is the results of the intra-ionic correlation and depends strongly on the charge distribution of hard-sphere ions.
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