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A gigantic polyoxozirconate with visible photoactivity.

Tingting Xu, Xudong Hou, Yang Wang, Jun Zhang, Junxiang Zhang, Bo Liu
Dalton Transactions : An International Journal of Inorganic Chemistry 2017 August 9
We present a gigantic polyoxozirconate nanocluster (Zr18 O21 (μ2 -OH)2 (OOCPh)28 ), involving 6, 7 and 8-coordinated Zr atoms. It exhibits visible light driven photocatalytic activity for H2 evolution. The current results could represent a prelude of polyoxozirconate-based photocatalysis.

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