We have located links that may give you full text access.
Two New Sandwich-Type Manganese {Mn5}-Substituted Polyoxotungstates: Syntheses, Crystal Structures, Electrochemistry, and Magnetic Properties.
Inorganic Chemistry 2017 August 8
Herein we report two pentanuclear MnII -substituted sandwich-type polyoxotungstate complexes, [{Mn(bpy)}2 Na(H2 O)2 (MnCl)2 {Mn(H2 O)}(AsW9 O33 )2 ]9- and [{Mn(bpy)}2 Na(H2 O)2 (MnCl){Mn(H2 O)}2 (SbW9 O33 )2 ]8- (bpy = 2,2'-bipyridine), whose structures have been obtained by single-crystal X-ray diffraction (SCXRD), complemented by results obtained from elemental analysis, electrospray ionization mass spectrometry, Fourier transform infrared spectroscopy, and thermogravimetric analysis. They consist of two [B-α-XW9 O33 ]9- subunits sandwiching a cyclic assembly of the hexagonal [{Mn(bpy)}2 Na(H2 O)2 (MnCl)2 {Mn(H2 O)}]9+ and [{Mn(bpy)}2 Na(H2 O)2 (MnCl){Mn(H2 O)}2 ]10+ moieties, respectively, and represent the first pentanuclear MnII -substituted sandwich-type polyoxometalates (POMs). Both compounds have been synthesized by reacting MnCl2 ·4H2 O with trilacunary Na9 [XW9 O33 ]·27H2 O (X = AsIII and SbIII ) POM precursors in the presence of bpy in a 1 M aqueous sodium chloride solution under mild reaction conditions. SCXRD showed that the alternate arrangement of three five-coordinated MnII ions and two six-coordinated MnII ions with an internal Na cation formed a coplanar six-membered ring that was sandwiched between two [B-α-XW9 O33 ]9- (X = AsIII and SbIII ) subunits. The results of temperature-dependent direct-current (dc) magnetic susceptibility data indicated ferromagnetic interactions between Mn ions in the cluster. Moreover, alternating-current magnetic susceptibility measurements with a dc-biased magnetic field showed the existence of a ferromagnetic order for both samples. Electrochemistry studies revealed the presence of redox processes assigned to the Mn centers. They are associated with the deposition of material on the working electrode surface, possibly Mnx Oy , as demonstrated by electrochemical quartz crystal microbalance experiments.
Full text links
Related Resources
Trending Papers
Heart failure with preserved ejection fraction: diagnosis, risk assessment, and treatment.Clinical Research in Cardiology : Official Journal of the German Cardiac Society 2024 April 12
Proximal versus distal diuretics in congestive heart failure.Nephrology, Dialysis, Transplantation 2024 Februrary 30
Efficacy and safety of pharmacotherapy in chronic insomnia: A review of clinical guidelines and case reports.Mental Health Clinician 2023 October
World Health Organization and International Consensus Classification of eosinophilic disorders: 2024 update on diagnosis, risk stratification, and management.American Journal of Hematology 2024 March 30
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app