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Diastereoselective synthesis of novel heterocyclic scaffolds through tandem Petasis 3-component/intramolecular Diels-Alder and ROM-RCM reactions.
Chemical Communications : Chem Comm 2017 August 23
A high-yielding, stereoselective and extraordinarily complexity-generating Petasis 3-component/intramolecular Diels-Alder reaction has been developed. In combination with ROM-RCM, rapid access to complex sp3 -rich heterocyclic scaffolds amenable to subsequent functionalization and library synthesis is provided.
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