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Annulated 1,3,4-Azadiphospholides: Heterocycles with Widely Tunable Optical Properties.
Angewandte Chemie 2017 September 5
Phosphorus heterocycles find applications in the synthesis of π-conjugated compounds and as precursors for optoelectronic materials such as organic light-emitting diodes (OLEDs), electronic switches, and transistors. A high-yield, one-pot synthesis of anionic annulated 1,3,4-azadiphospholides from Na(OCP) and 2-chloropyridines is presented. The synthesis proceeds without the use of transition metals and tolerates a wide range of substrates. Cyano-substituted compounds are especially deeply colored and have absorption maxima which range from λmax =525 to 596 nm. The optical properties are dominated by the spatial separation of an electron acceptor and donor unit within one molecule (push-pull chromophore). The anionic 1,3,4-azadiphospholides are silylated to neutral siloxy compounds with a strong blue-shifted absorption. This reaction can be reversed by addition of fluoride ions, which allows fluoride ions to be detected in optically low concentrations.
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