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Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex.
Angewandte Chemie 2017 August 29
Regio- and enantioselective [4+2] annulation between β,γ-unsaturated α-keto esters and non-activated allenes was achieved by using a chiral cationic indium(III)/phosphate catalyst. The reaction affords the corresponding C3-selective dihydropyrans in good yields and with high enantioselectivity (up to 99 % ee).
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