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An unprecedented trinuclear Fe II triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature.
Chemical Communications : Chem Comm 2017 July 21
We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS-HS-HS] ↔ [LS-LS-LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transition in this trinuclear complex.
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