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Acidity Strength of Solid Catalysts Probed by Hyperpolarized Natural Abundance (17) O NMR Spectroscopy.

Frédéric Blanc
Angewandte Chemie 2017 September 19
Observation of Brønsted acid sites: By enhancing the solid-state NMR signals of (17) O at natural abundance with dynamic nuclear polarization (DNP), Pruski et al. were able to measure oxygen-proton distances accurately with sub-picometer precision. The results give insight into the Brønsted acidity of a range of solid acid catalysts.

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