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Cu-Catalyzed Aminodifluoroalkylation of Alkynes and α-Bromodifluoroacetamides.

Yunhe Lv, Weiya Pu, Qian Chen, Qingqing Wang, Jiejie Niu, Qian Zhang
Journal of Organic Chemistry 2017 August 5
The copper-catalyzed highly regioselective aminodifluoroalkylation of alkynes and α-bromodifluoroacetamides was realized for the first time. With this method, 3,3-difluoro-1H-pyrrol-2(3H)-ones were constructed in a single step from various alkynes and α-bromodifluoroacetamides substrates without using any extra oxidant.

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