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A mechano-responsive supramolecular metal-organic framework (supraMOF) gel material rich in ZIF-8 nanoplates.
Chemical Communications : Chem Comm 2017 July 28
We report an unconventional ZIF-8 based supramolecular MOF (supraMOF) material, which is straightforwardly synthesised by leveraging the high concentration reaction (HCR) approach. Akin to traditional low-molecular-weight gels (LMWG), we show that mechano-stimulus responsive behaviour can be achieved through a reversible and fast sol-gel conversion mechanism. Remarkably, the supraMOF gel consists of 2D nanoplates of ZIF-8 with a reduced crystal symmetry.
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