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Exploiting Pincer Ligands to Perturb the Geometry at Boron.
Chemistry : a European Journal 2017 August 5
Boranes are ubiquitous in synthesis and materials but advancements in their development have been primarily restricted to the geometric energetic minima, trigonal planar complexes. This report discloses a class of boranes with expanded bond angles achieved by taking advantage of the structural rigidity of tridentate pincer ligands. The bonding of these novel boranes is investigated by X-ray crystallography and computationally.
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