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Gold(iii)-arene complexes by insertion of olefins into gold-aryl bonds.
Chemical Science 2017 June 2
The synthesis and characterization of the first gold(iii)-arene complexes are described. Well-defined (P,C)-cyclometalated gold(iii)-aryl complexes were prepared and characterized by NMR spectroscopy. These complexes swiftly and cleanly reacted with norbornene and ethylene to provide cationic gold(iii)-alkyl complexes, in which the remote phenyl ring was η(2)-coordinated to gold. The interaction between the aromatic ring and the gold(iii) center was thoroughly analyzed by NMR spectroscopy, X-ray diffraction, and DFT calculations. The π-arene coordination was found to significantly influence the stability and reactivity of low coordinated gold(iii) alkyl species.
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