Commendable Eu 2+ -Doped Oxide-Matrix-Based LiBa 12 (BO 3 ) 7 F 4 Red Broad Emission Phosphor Excited by NUV Light: Electronic and Crystal Structures, Luminescence Properties.

In this work, we synthesized a new Eu2+ -doped oxide-matrix-based LiBa12 (BO3 )7 F4 broad red emission phosphor. It can emit red light peaking at ∼644 nm under NUV excitation with the coordinate at (0.6350, 0.3586) and a sensitive color gamut for eyes. This phosphor with a special kind of tunnel crystal structure and layered distribution of Ba2+ is contributed to longer wavelength emission. By theoretical calculation and analysis using local state density energy band structure simulation of Eu2+ doped in different site, the origin of the observed emission center was distinguished. Furthermore, decay curves analysis also indicated there are three possible Ba2+ sites for Eu2+ to occupy. Temperature-dependent PL spectra appeared anomalous phenomena that the intensity increases first and then decreases, which is due to the traps energy level's contribution of electron's transition. The phosphor also has cathodoluminescence (CL) property which the spectra take on typical current saturation phenomenon. The CL curves indicated that this phosphor has a very good stability under much electron beam bombardment time. After fabricated combining with BAM, (Sr, Ba)2 SiO4 and our red phosphor excited under 405-nm NUV chips, warm light LED was obtained. Its CIE coordinate is (0.3475, 0.3416) and the CCT, Ra, and luminous efficiency are 4856 K, 84.1, and 72.6 lm/W, respectively.