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Controllable Interlayer Spacing of Sulfur-Doped Graphitic Carbon Nanosheets for Fast Sodium-Ion Batteries.
Small 2017 June 27
The electrochemical behaviors of current graphitic carbons are seriously restricted by its low surface area and insufficient interlayer spacing for sodium-ion batteries. Here, sulfur-doped graphitic carbon nanosheets are reported by utilizing sodium dodecyl sulfate as sulfur resource and graphitization additive, showing a controllable interlayer spacing range from 0.38 to 0.41 nm and a high specific surface area up to 898.8 m(2) g(-1) . The obtained carbon exhibits an extraordinary electrochemical activity for sodium-ion storage with a large reversible capacity of 321.8 mAh g(-1) at 100 mA g(-1) , which can be mainly attributed to the expanded interlayer spacing of the carbon materials resulted from the S-doping. Impressively, superior rate capability of 161.8 mAh g(-1) is reserved at a high current density of 5 A g(-1) within 5000 cycles, which should be ascribed to the fast surface-induced capacitive behavior derived from its high surface area. Furthermore, the storage processes are also quantitatively evaluated, confirming a mixed storage mechanism of diffusion-controlled intercalation behavior and surface-induced capacitive behavior. This study provides a novel route for rationally designing various carbon-based anodes with enhanced rate capability.
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