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An enantioselective cascade for simultaneous generation of five quaternary stereocenters from fully substituted enones.
Chemical Communications : Chem Comm 2017 July 5
A highly enantioselective cascade reaction for the generation of five quaternary stereocenters in one-pot operation is reported for the first time in the history of organic synthesis. Cinchona-alkaloid derived hydrogen-bonding catalyst furnished structurally complex cascade products from simple substrates in excellent yields and stereoselectivities.
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