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Synthesis and characterization of catalytically active thiazolium gold(i)-carbenes.

Clément C Dince, Roy A Meoded, Donald Hilvert
Chemical Communications : Chem Comm 2017 July 5
Thiamin analogs were used to synthesize mono gold(i)-carbene derivatives in a single step under aqueous conditions. The resulting thiazolium gold(i)-carbenes catalyze 5-endo-dig carbocyclization of an acetylenic dicarbonyl compound in organic solvents and hydroalkoxylation of an allene in aqueous buffer.

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