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Cation-Driven Self-Assembly of a Gold(I)-Based Metallo-tweezer.
Angewandte Chemie 2017 June 20
A combination of self-complementary π-π-stacking interactions and metallophilic interactions triggered the self-assembly of a new digold(I) metallo-tweezer in the presence of several types of M(+) ions. Titrations by fluorescence spectroscopy enabled the determination of the association constants of the resulting inclusion duplex complexes.
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