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Journal Article
Research Support, Non-U.S. Gov't
Rhodium(III)-Catalyzed Selective C-H Acetoxylation and Hydroxylation Reactions.
Organic Letters 2017 July 8
An efficient Cp*Rh(III)-catalyzed, chelation-assisted C(sp2 )-H acetoxylation and hydroxylation reaction has been developed for the first time. The reaction proceeds under mild conditions and allows for selective preparation of C-H acetoxylation and hydroxylation products, thus providing a good complement to previous C-H oxygenation reactions and expanding the field of Cp*Rh(III)-catalyzed C-H functionalizations.
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