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Enhancement of the antiproliferative activity of [RuCp(PPh 3 ) 2 (dmoPTA-1κP)] + via its coordination to one {CoCl 2 } unit: synthesis, crystal structure and properties of [RuCp(PPh 3 ) 2 -μ-dmoPTA-1κP:2κ 2 N,N'-CoCl 2 ](OTf)·0.25H 2 O.
Synthesis, characterization and the antiproliferative activity of a new bimetallic complex [RuCp(PPh3 )2 -μ-dmoPTA-1κP:2k2 N,N'-CoCl2 ]OTf·0.25H2 O are described. The stability of the complex was studied under air and N2 atmospheres and in CDCl3 , DMSO, water and the cell culture medium, at room temperature and 40 °C. The complex showed an enhanced antiproliferative activity (up to six-fold) when compared with its parent complex [RuCp(PPh3 )2 (HdmoPTA)]2+ against human lung, cervix, breast, and colon solid tumor cell lines.
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