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Generation and characterisation of a stable nickel(ii)-aminoxyl radical complex.
A stable nickel(ii)-aminoxyl radical complex was generated by the reaction of a nickel(ii) complex supported by a tren ligand (tris(2-aminoethyl)amine) having bulky m-terphenyl substituents (TIPT: 3,5-bis(2,6-diisopropylphenyl)phenyl) and m-CPBA (m-chloroperoxybenzoic acid). The formation mechanism of the nickel(ii)-aminoxyl radical complex was examined.
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