Add like
Add dislike
Add to saved papers

An iron germylene complex having Fe-H and Ge-H bonds: synthesis, structure and reactivity.

A base-free iron germylene complex Cp*(CO)(H)Fe[double bond, length as m-dash]GeH{C(SiMe3 )3 } (1) was synthesised by abstraction of pyridine from a germyl complex Cp*(CO)(py)FeGeH2 {C(SiMe3 )3 } (2), which was prepared by treatment of Cp*Fe(CO)(py)(Me) with H3 GeC(SiMe3 )3 . X-ray crystallographic analysis revealed that 1 has an Fe-Ge bond that is the shortest among those ever reported. Reactivity of 1 toward several polar unsaturated organic compounds was investigated. Complex 1 underwent stoichiometric hydrogermylation of carbonyl compounds such as ketones, aldehydes and isocyanates (RNCO) at room temperature. In contrast, the reactions of 1 with isothiocyanates (RNCS) resulted in clean cleavage of the C[double bond, length as m-dash]S double bonds.

Full text links

We have located links that may give you full text access.
Can't access the paper?
Try logging in through your university/institutional subscription. For a smoother one-click institutional access experience, please use our mobile app.

For the best experience, use the Read mobile app

Mobile app image

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app

All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.

By using this service, you agree to our terms of use and privacy policy.

Your Privacy Choices Toggle icon

You can now claim free CME credits for this literature searchClaim now

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app