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Stepwise self-assembly of a discrete molecular honeycomb using a multitopic metallo-organic ligand.
Chemical Communications : Chem Comm 2017 June 21
Self-assembly of a metallo-organic ligand, composed of an inner uncomplexed 120°-bis(terpyridine) and an outer extended free 120°-bis(terpyridine) linked by a triple 〈-tpy-Ru2+ -tpy-〉 connector, and complexed with Zn2+ , gave rise to a discrete planar supramolecular honeycomb patterned fractal. The central metallo-hexagon was surrounded by six identical metallo-hexagons which perfectly mimicked the natural simple honeycomb structure.
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