We have located links that may give you full text access.
Electronic Spectra of Tris(2,2'-bipyridine)-M(II) Complex Ions in Vacuo (M = Fe and Os).
Inorganic Chemistry 2017 June 20
We measured the electronic spectra of mass-selected [M(bpy)3 ]2+ (M = Fe and Os, bpy = 2,2'-bipyridine) ions in vacuo by photodissociation spectroscopy of their N2 adducts, [M(bpy)3 ]2+ ·N2 . Extensive band systems in the visible (predominantly charge transfer) and near-ultraviolet (ππ*) spectral regions are reported. The [M(bpy)3 ]2+ ·N2 target ions were prepared by condensing N2 onto electrosprayed ions in a cryogenic ion trap at ca. 25 K and then mass-selected by time-of-flight mass spectrometry. The electronic photodissociation spectra of the cold, gas-phase ions closely reflect their intrinsic properties, i.e., without perturbation by solvent effects. The spectra are interpreted using time-dependent density functional theory calculations both with and without accounting for relativistic effects.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app