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Journal Article
Research Support, Non-U.S. Gov't
A Palladium-Catalyzed α-Arylation of Oxindoles with Aryl Tosylates.
Journal of Organic Chemistry 2017 June 17
A palladium-catalyzed monoselective C3 arylation of 2-oxindoles with aryl tosylates is described. With the Pd/CM-phos catalyst system, the corresponding 3-arylated oxindoles can be obtained in good to excellent yields (≤97%). The reaction conditions are mild (using 0.5 mol % Pd in general and KF as a base), and functional groups such as methyl ester, NH amido, and enolizable keto moieties are found to be compatible.
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