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Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru-Mn(iii) 1D cyanide-bridged complexes.
A new one-dimensional cyanide-bridged complex [MnIII (salphen)RuII (DMAP)4 (CN)2 ](PF6 ) (1) and its oxidized derivative [MnIII (salphen)RuIII (DMAP)4 (CN)2 ](PF6 )2 (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow magnetic relaxation.
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