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An Efficient Blue-Emissive Metal-Organic Framework (MOF) for Lanthanide-Encapsulated Multicolor and Stimuli-Responsive Luminescence.

A novel blue-emitting Zn(II) MOF featuring parallel 2D+2D interpenetrated layers and tubelike channels was generated and shown to efficiently accommodate lanthanide(III) cations (Ln3+ = Eu3+ , Tb3+ , or a mixture of Eu3+ /Tb3+ ), resulting in the Ln3+ -encapsulated functional materials with a tunable emission color, including red, green, and nearly pure white light. Furthermore, the thermal-responsive luminescence was investigated for the lanthanide-codoped MOF to exhibit the chromic transition from white at room temperature to blue around liquid nitrogen temperature.

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