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A designer ligand field for blue-green luminescence of organoeuropium(ii) sandwich complexes with cyclononatetraenyl ligands.
Chemical Communications : Chem Comm 2017 June 22
A novel η9 -coordinated double-decker sandwich complex of divalent europium is synthesized. The complex exhibits blue-green photoluminescence at 516 nm, which is significantly blue-shifted from those of other organoeuropium(ii) sandwich complexes (∼630 nm). The blue-shift was quantitatively explained by the weakened electrostatic field of the expanded 10-π ring.
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