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A zwitterionic hydrocarbon-soluble borenium ion based on a β-diketiminate backbone.
Chemical Communications : Chem Comm 2017 May 31
A versatile synthetic route has been developed to access strongly Lewis acidic borenium cations (and heavier group 13 analogues) featuring a pendant weakly-coordinating borate function. The hydrocarbon-soluble borenium/borate zwitterion is more strongly Lewis acidic than B(C6 F5 )3 , despite featuring a pendant (non-fluorinated) aryl group and two flanking N-donors.
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