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Copper-catalyzed remote (δ) C(sp 3 )-H bond amination: a practical strategy to construct pyrrolidine derivatives.
Chemical Communications : Chem Comm 2017 May 26
We report a copper-catalyzed remote C(sp3 )-H bond amination reaction that converts acyclic amines to pyrrolidines. This reaction occurs selectively at the carbon δ to the amine functionality. Primary, secondary and tertiary C-H bonds are all suitable for the amination reactions in the presence of an inexpensive and commercially available copper catalyst.
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