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A novel metal-free method for the selenocyanation of aromatic ketones to afford α-carbonyl selenocyanates.
Organic & Biomolecular Chemistry 2017 May 24
A new method has been developed for the selenocyanation of aromatic ketones. This reaction avoids the need to use pre-prepared α-halo ketones, providing rapid access to α-carbonyl selenocyanates. We also investigated the mechanism for this reaction and found that it proceeds via sequential radical iodination and nucleophilic substitution reactions.
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