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Ultrafast Delamination of Graphite into High-Quality Graphene Using Alternating Currents.
Angewandte Chemie 2017 June 2
To bridge the gap between laboratory-scale studies and commercial applications, mass production of high quality graphene is essential. A scalable exfoliation strategy towards the production of graphene sheets is presented that has excellent yield (ca. 75 %, 1-3 layers), low defect density (a C/O ratio of 21.2), great solution-processability, and outstanding electronic properties (a hole mobility of 430 cm(2) V(-1) s(-1) ). By applying alternating currents, dual exfoliation at both graphite electrodes enables a high production rate exceeding 20 g h(-1) in laboratory tests. As a cathode material for lithium storage, graphene-wrapped LiFePO4 particles deliver a high capacity of 167 mAh g(-1) at 1 C rate after 500 cycles.
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